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Question

Wilkinson's catalyst [Rh(Ph3P)3Cl] is used for:


A
hydrogenation of oils
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B
hydrogenation of alkynes
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C
hydrogenation of alkenes
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D
polymerisation of alkenes
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Solution

The correct option is B hydrogenation of alkenes
Wilkinson's Catalyst [Rh(Ph3P)3]Cl is used for hydrogenation of alkenes.

The rhodium is able to form a 6-coordinate complex, allowing it to selectively reduce alkenes. The Wilkinson's catalyst is not able to reduce carbon-oxygen double bonds or double bonds, and it selectively reduces the least hindered double bond.

Option C is correct.

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