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Question

With respect to halogens, four statements are given below. Which of them is correct?

A
The bond dissociation energies for halogens is in the order : I2<F2<Br2<Cl2
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B
The only oxidation state is -1
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C
The amount of energy required for the excitation of electrons to first excited state decreases progressively as we move from F to 1
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D
They form HX2 species in their aqueous solutions (X=halogen)
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Solution

The correct option is A The bond dissociation energies for halogens is in the order : I2<F2<Br2<Cl2

The bond dissociation energy of halogens is given in order: I2<F2<Br2<Cl2.

The bond dissociation energy decreases down the group, but fluorine shows remarkably small dissociation energy.

In halogens, there are two bonding pair and 3 nonbonding pairs. Because of the small size of fluorine, these non-bonding pairs come closer to each other and repel each other to a maximum extent which causes a decrease in bond strength.


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