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Question

With the given anions, the correct stability order of tetrahaloborates is:

A
BCl4>BBr4>BI4
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B
BI4>BBr4>BCI4
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C
BCl4=BBr4>BI4
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D
BCl4=BBr4=BI4
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Solution

The correct option is B BI4>BBr4>BCI4
In BX3, pπpπ back bonding takes place. The back bonding is stronger in case of BF3 and reduces progressively down the series. This makes the formation of the coordinate bond XBX3 more difficult.

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