Rule for balancing equation ion electron method :-
1. Write down unbalanced equation.
2. Assign oxidation number for all and separate into two half reaction
[i− oxidation half reaction
ii− reduction half reaction]
3. Balanced all the elements except O,H
4. Balance oxygen atom with H2O
5. Balance hydrogen atoms with H+
6. Balance charge on both sides and multiply with equivalent number to cancel out electrons on each side.
7. Simplify and verify the reaction
3HNO2⇌NO−3+2NO+H++H2O