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Question

Write chemical equations to represent the following reactions:
(a) The dissolving of PbO in NaOH(aq).
(b)The disproportionate of SnO to Sn and SnO2.
(c) The oxidation of HCl(aq) to Cl2(g) by PbO2(s).
(d)The production of basic lead carbonate (white lead) 2PbCO3Pb(OH)2 by the action of H2O and CO2 on PbO.

A
(a) PbO+NaOH+H2ONa[Pb(OH)3]; (b) 2SnOSn+SnO2; (c) PbO2+4HClPbCl2+2H2O+Cl2; (d) 2PbO+H2O+CO2PbCO3Pb(OH)2
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B
(a) PbO+NaOH+H2ONa[Pb(OH)2]OH; (b) 2SnOSn+SnO2; (c) PbO2+4HClPbCl2+2H2O+Cl2; (d) 3PbO+H2O+CO22PbCO3Pb(OH)2
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C
(a) PbO+NaOH+H2ONa[Pb(OH)](OH)2; (b) 2SnOSn+SnO2; (c) PbO2+4HClPbCl2+2H2O+Cl2; (d) 3PbO+2H2O+CO22PbCO3Pb(OH)2
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D
(a) PbO+NaOH+H2ONa[Pb(OH)3]; (b) 2SnOSn+SnO2; (c) PbO2+3HClPbCl2+H2O+Cl2; (d) 3PbO+H2O+CO22PbCO3Pb(OH)2
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Solution

The correct option is A (a) PbO+NaOH+H2ONa[Pb(OH)3]; (b) 2SnOSn+SnO2; (c) PbO2+4HClPbCl2+2H2O+Cl2; (d) 2PbO+H2O+CO2PbCO3Pb(OH)2
The balanced reactions are as follows:
(i) PbO+NaOH+H2ONa[Pb(OH)3]
(ii) 2SnOSn+SnO2
(iii) PbO2+4HClPbCl2+2H2O+Cl2

(iv) 2PbO+H2O+CO2PbCO3Pb(OH)2

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