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Question

Write chemical reactions for different steps in the manufacture of sulphuric acid by lead chamber process. Draw the structure of phosphorus pentachloride.

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Solution

Structure of PCl5

Lead chamber process
1) First SO2 is formed
S+O2SO2
OR
FeS2+O2Fe2O3+SO2
2) H2SO4 is obtained by oxidation of SO2 in presence of NO as a catalyst.
SO2+H2O+[O]NOH2SO4

1213798_1561204_ans_217dc1a630474437bdf25526cf09a98f.png

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