Write correct reactivity order towards photochemical chlorination.

X > Y > Z > W

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Y> Z > X > W

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X > Z > W > Y

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Z > W > Y > X

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Solution

The correct option is B Y> Z > X > W
The product mixture found experimentally for 2>3>1from Proportion of composition found for alkyl halides are 33%>22%>15%. These depend on the activation energies found by the Arrhenius equation. The greater the difference between activation energies,larger the selectivity.

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