Ozone is naturally produced in the stratosphere by a two-step reactive process. In the first step, solar ultraviolet radiation (sunlight) breaks apart an oxygen molecule to form two separate oxygen atoms. In the second step, each atom then undergoes a binding collision with another oxygen molecule to form an ozone molecule. In the overall process, three oxygen molecules plus sunlight react to form two ozone molecules. Overall reaction :
O2 + ℎνuv → 2O.
O. + O2 ↔ O3