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Question

Write IUPAC name of the complex [Co(en)2(H2O)(CN)]2+.

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Solution

Oxidation state of Co in the given compound-

x+(2×0)+0+(1)=+2

x=2+1=+3

Oxidation state of cobalt in the given compound is +3.

The compound has 4 ligands-

1 aqua ligand (H2O)

1 cyano ligand (CN)

2 ethylene-di-amine ligands (en)

Thus the IUPAC name of the given compound is aquacyanobis-(ethylenediamine)cobalt (III) ion.

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