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Question

Write the cell reaction and calculate the e.m.f. of cell for Cl2(1atm)|NaCl(aq)|Cl2(0.1atm). Will the cell reaction be spontaneous?

A
-0.0295, Non-spontaneous
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B
-0.0295, spontaneous
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C
0.0295, Non-spontaneous
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D
0.0295, spontaneous
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Solution

The correct option is A -0.0295, Non-spontaneous
Cl2(1atm)|NaCl(aq)|Cl2(0.1atm)
as we know,
E=0.059/2log(0.1/1)=0.0295
as E< 0 so its a non-spontaneous reaction.

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