Write the cis and trans isomeric structure of $[F e (N H_{3})_{2} (C N)_{4}]^{-}$ .

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Solution

The structures for the cis and trans isomers of $[F e (N H_{3})_{2} (C N)_{4}]^{-}$ are as shown. In the cis isomer, two ammonia ligands are adjacent to each other. In the trans isomer, two ammonia ligands are opposite to each other.

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[C o (N H_{2} - C H_{2} - C H_{2} - N H_{2})_{2} C l_{2}]^{+}, [C r C l_{2} (C_{2} O_{4})_{2}]^{3 -}, [F e (H_{2} O)_{4} (O H)_{2}]^{+}, [F e (N H_{3})_{2} (C N)_{4}]^{-}, [C o (N H_{2} - C H_{2} - C H_{2} - N H_{2})_{2} (N H_{3}) C l]^{2 +}

[C o (N H_{3})_{4} (H_{2} O) C l]^{2 +}

[C o (N H_{2} - C H_{2} - C H_{2} - N H_{2})_{2} C l_{2}]^{+}, [C r C l_{2} (C_{2} O_{4})_{2}]^{3 -}, [F e (H_{2} O)_{4} (O H)_{2}]^{+}, [F e (N H_{3})_{2} (C N)_{4}]^{-}, [C o (N H_{2} - C H_{2} - C H_{2} - N H_{2})_{2} (N H_{3}) C l]^{2 +}

[C o (N H_{3})_{4} (H_{2} O) C l]^{2 +}

Draw the cis and trans structures of hex-2-ene. Which isomer will have higher b.p. and why?

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