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Question

Write the co-ordination number of each ion in the following crystals.

A
NaCl
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B
CsCl
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C
ZnS
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D
CaF2
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E
Na2O
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Solution

The correct option is B NaCl
NaCl6 (each Na is surrounded by 6 Cl)
Cation occupies half of the tetrahedral voids; anion forms FCC.
CsCl8 (each Cs is surrounded by 8Cl)
Cation occupies body center, anion forms BCC
Zns4 Cation occupies alternate tetrahedral voids; anion forms FCC.
CaF24 Cation occupies alternate body center; anion forms BCC.

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