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Question

Write the definition of acid and base based on Arrhenius principle and write the limitations of this principle.

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Solution

Acid is substance containing hydrogen which produces hydrogen ion (H+) in its aqueous solution.
Base is a substance containing hydroxide which produces hydroxide ion (OH) in its aqueous solution.
Limitations of Arrhenius AcidBase Theory:
It is applicable to aqueous solutions.
Ammonia does not contain hydroxide ion, still its aqueous solution acts as a base.
H+ ion cannot exist independently, so it combines with a water molecule to form hydronium ion (H3O+).

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