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Question

Write the difference between order and molecularity of a reaction.

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Solution

Difference between order and molecularity of a reaction-
Order of reaction Molecularity of reaction
It is defined as the sum of powers of concentration terms in a rate equation. It is defined as no. of molecules or atoms or ions participating in a rate determining step.
It is an experimental quantity. It is a theoretical concept.
It varies with a change in temperature. It is independent of temperature.
It may be a whole number, a fraction or zero. It is always a whole number.
It is obtained through experimentation and is dependent upon the rate for the overall reaction.It is obtained from the simple balance chemical equation.

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