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Question

Write the differences between acetaldehyde and benzaldehyde.

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Solution

Reactions Acetaldehyde
CH3CHO
Benzaldehyde
C6H5CHO
(1) Heating with
Fehling's solution
gives a red
precipitate
no reaction
(2) With ammoniaforms simple addition
product
forms complex, condensation
product
(3) With caustic
soda
undergoes Aldol
product
undergoes Cannizzaro
reaction
(4) With primary
amines
does not form Schiff's
base
forms Schiff's base
(5) With chlorinedoes not form acetyl
chloride
forms benzoyl chloride
(6) Polymerisation undergoes polymerisation does not polymerise
(7) Electrophilic
substitution
does not under go undergo at meta position
(8) With Schiff's
reagent
gives pink colour in
cold
gives pink colour

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