Write the following reactions
(i) Carbylamine reaction
(ii) Iodoform reaction
(iii) Frankland reaction
(iv) Fitting reaction

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Solution

(i) Carbylamine reaction: On heating chloroform with primary amine (e.g. animline) and alcoholic KOH solution, phenylisocyanide or carbylamine is formed which has a very bad smell and is poisonous.
$C_{6} H_{5} - N H_{2} + C H C l_{3} + K O H A n i l i n e \to C_{6} H_{5} \to = C + 3 K C l + 3 H_{2} O P h e n y l i s o c y a n i d e$
Application: Chloroform and primary amine can by tasted by this reaction.
(ii) Iodoform reaction: When acetone or alcohol heating with iodine and sodium hydro-oxide form the Iodoform.
$C H_{3} C O C H_{3} + 4 N a O H + 3 I_{2} \to C H I_{3} + C H_{3} C O O N a + 3 N a I + 3 H_{2} O$
(iii) Frankland reaction: This reaction is likely to wurtz reaction. In this reaction we use zink inplace of sodium.
$R I + Z n + I R \to □ R - R + Z n I_{2}$
(iv) Fitting reaction: When haloalkanes area heated with sodium metal and haloalkanes in ethereal solution the halogen atom is replaced by alkye group and two phenyl rings unite forming diphenye
$C_{6} H_{5} C l + 2 N a + C l - C_{2} H_{5} D r y e t h e r - ---- \to C_{6} H_{5} - C_{6} H_{5} + 2 N a C l$

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Similar questions

Q. The following reaction is an example of a:

4 N H_{3} (g) + 5 O_{2} (g) \to 4 N O (g) + 6 H_{2} O (l)

(i) displacement reaction
(ii) combination reaction
(iii) redox reaction
(iv) neutralisation reaction

The following reaction is an example of a
$2 P b (N O_{3})_{2} (s) H e a t - -- \to 2 P b O (s) + 4 N O_{2} (g) + O_{2} (g)$
I. Combination reaction
II. Decomposition reaction
III. Endothermic reaction
IV. Exothermic reaction

Q. The reaction between carbon and oxygen can be represented as

C_{(s)} + O_{2 (g)} \to C O_{2 (g)} + h e a t

In which of the following type(s), the above reaction can be classified?
I. Combustion reaction
II. Displacement reaction
III. Endothermic reaction
IV. Combination reaction.

Q. Question 2

The following reaction is an example of a

4 {NH}_{3} (g) + 5 O_{2} (g) \to 4 NO(g) + 6 H_{2} O(g)

(i) Displacement reaction
(ii) Combination reaction
(iii) Redox reaction
(iv) Neutralisation reaction

(a) (i) and (iv)
(b) (ii) and (iii)
(c) (i) and (iii)
(d) (iii) and (iv)

Identify the types of reactions:-

(i) $H_{2} (g) + C l_{2} (g) \to 2 H C l (g)$

(ii) $N a O H (a q) + H C l (a q) \to N a C l (a q) + H_{2} O (l)$

(iii) $F e (s) + S (s) h e a t - - \to F e S (s)$

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Write the following reactions(i) Carbylamine reaction(ii) Iodoform reaction(iii) Frankland reaction(iv) Fitting reaction

Write the following reactions
(i) Carbylamine reaction
(ii) Iodoform reaction
(iii) Frankland reaction
(iv) Fitting reaction