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Question

Write the following reactions:
(i) Clemmensen reduction
(ii) Perkins reaction

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Solution

(i) Clemmensen reduction
Carbonyl group (of aldehydes and ketones) is reduced to methylene group by treatment with zinc amalgam and conc. HCl.
(ii) Perkins reaction
The aldol condensation of an aromatic aldehyde with an acid anhydride gives
a α,βunsaturated aromatic acid (cinnamic acid).
773993_757037_ans_d945d9df275746cfb34488555713bc69.png

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