The correct option is A Cl2O7
The formula for an oxide of chlorine with Cl in the oxidation state +7 is Cl2O7.
The oxidation number of O is −2. Hence, the oxidation number of Cl in Cl2O7 is +7.
The oxidation number of Cl in Cl3O5,Cl3O7 and Cl2O5 is +3.33, 143 and +5 respectively.