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Question

Write the IUPAC name of the compound from their given structure.
(a)

(b)

(c)

(d)

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Solution

(a) Step 1: Identification of functional group
The functional group present in the given structure is an alcohol (OH). Hence, the suffix is '-ol'.

Step 2 : IUPAC name
The longest chain containing OH has eight carbon atoms. Hence, the parent hydrocarbon is octane.
The OH is on 3rd carbon and a substitute methyl group is attached at 6th carbon. Hence, the IUPAC name of this compound is 6Methyloctan-3-ol..

Final answer:
6Methyloctan-3-ol.

(b) Step 1 : Identification of functional group
The functional group present in the given structure is ketone (>C=O), hence suffix '-one'. Presence of two keto groups is shown by 'di', hence suffix becomes 'dione'.

Step 2 : IUPAC name
The two keto groups are at carbons 2nd and 4th. The longest chain contains 6 carbon atoms; hence, parent hydrocarbon is hexane. Thus, the IUPAC name of this compound is Hexane- 2,4-dione.

Final answer:
Hexane- 2,4-dione

(c) Step 1 : Identification of functional group
Here, two functional groups namely ketone and carboxylic acid are present. The principal functional group is the carboxylic acid group: hence the parent chain will be suffixed with 'oic' acid.

Step 2 : IUPAC name
Numbering of the chain starts from carbon of -COOH functional group. The keto group in the chain at carbon 5th is represent by 'oxo'.
The longest chain including the principal functional group has 6 carbon atoms; hence, the parent hydrocarbon is hexane. Thus, the IUPAC name of this compound is 5Oxohexanoic acid.

Final answer:
5Oxohexanoic acid

(d) Step 1 : Identification of functional group
The two C=C functional groups are present at carbon atoms 1st and 3rd, while the CC functional group is present at carbon 5th. These groups are represented by suffixes 'diene' and 'yne' respectively.

Step 2 : IUPAC name
The longest chain containing the functional groups has 6 carbon atoms; hence the parent hydrocarbon is hexane. Hence, the IUPAC name of this compound is Hexa-1,3-dien-5-yne.

Final answer:
Hexa-1,3-dien-5-yne.


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