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Nomenclature of Coordination Compounds

Write the IUP...

Question

Write the IUPAC names of the following coordination compounds:
(i) $[C r {({N H}_{3})}_{4} {(H_{2} O)}_{2}] {C l}_{3}$
(ii) $[P t {C l}_{2} {({N H}_{3})}_{4}] [P t {C l}_{4}]$

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Solution

(i) tetraamminediaquachromium ( $I I I$ ) chloride
(ii) tetraamminedichloroplatinum ( $I V$ ) tetrachloroplatinate ( $I I$ )

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[C r (N H_{3})_{3} C l_{3}]

K_{3} [F e (C N)_{6}]

[C o B r_{2} (e n)_{2}]^{+}

K_{2} [Z n (O H)_{4}]

[C o (N H_{3})_{5} (C O_{3})] C l

K [A g {(C N)}_{2}]

K_{4} [F e {(C N)}_{6}]

[A g {(N H_{3})}_{2}] C l

[C r {(N H_{3})}_{6}] {C l}_{3}

[C o (N H_{3})_{6}] C l_{3}

K_{3} [F e (C N)_{6}]

K_{2} [P d (C l)_{4}]

[N i (C o)_{4}]

Write the IUPAC names of the following coordination compounds:

(i) [Co(NH₃)₆]Cl₃

(ii) [Co(NH₃)₅Cl]Cl₂

(iii) K₃[Fe(CN)₆]

(iv) K₃[Fe(C₂O₄)₃]

(v) K₂[PdCl₄]

(vi) [Pt(NH₃)₂Cl(NH₂CH₃)]Cl

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