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Question

Write the IUPAC names of the following :
[Ag(NH3)2][Ag(CN2)]

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Solution

In this complex, the Cation is [Ag(NH3)2]+ ion.

The Anion [Ag(CN)2] ion

Name of Cation

= Diammine silver(I) ion

Name of Anion

=Dicyano argentate(I)ion

The name of the complex is

=DIAMMINE Silver(I) Dicyano Argentate (I)

Here NH3 is a neutral ligand and CN is a negative ligand.

So the OXIDATION-NUMBER of Ag=+1


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