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Introduction to CFT

Write the IUP...

Question

Write the IUPAC nomenclature of the given complex along with its hybridization and structure.
$K_{2} [C r (N O) (N H_{3}) (C N)_{4}]$ , Spin magnetic moment $(μ) = 1.73$

A

potassium amminetetracyanonitrosochromate (III) ,

d^{2} s p^{3}

, octahedral

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B

potassium ammoniatetracyanonitrosochromate (I) ,

s p^{3}

, tetrahedral

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C

potassium amminetetracyanonitrosochromate (I) ,

d^{2} s p^{3}

, octahedral

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D

potassium ammoniatetracyanonitritochromate (I) ,

s p^{3}

, octahedral

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Solution

The correct option is C potassium amminetetracyanonitrosochromate (I) , $d^{2} s p^{3}$ , octahedral

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Similar questions

Q. Which of the following statements is incorrect for the coordination compound :

K_{2} [C r (N O) (N H_{3}) (C N)_{4}]

?

Q. Which of the following statements is incorrect for the coordination compound :

K_{2} [C r (N O) (N H_{3}) (C N)_{4}]

?

Q. Match the examples given in column I with the shapes of the compounds given in column II and mark the appropriate choice.

	Column I		Column II
(A)	$[A g (N H_{3})_{2}]^{+}$	(i)	$d^{2} s p^{3},$ octahedral
(B)	$[N i (C N)_{4}]^{2 -}$	(ii)	$d s p^{2}$ , square planar
(C)	$[N i (C O)_{4}]$	(iii)	$s p$ , linear
(D)	$[F e (C N)_{6}]^{3 -}$	(iv)	$s p^{3}$ , tetrahedral

Q. Match list-I (Complexes) with list - II (Hybridization of Central Atom) and select the correct answer using the codes given below the lists :

	List - I		List - II
A.	$[N i (C O)_{4}]$	1.	$s p^{3}$
B.	$[N i (C N)_{4}]^{2 -}$	2.	$d s p^{2}$
C.	$[F e (C N)_{6}]^{4 -}$	3.	$s p^{3} d^{2}$
D.	$[M n F_{6}]^{4 -}$	4.	$d^{2} s p^{3}$
		5.	$s p^{2} d$

Q. Which of the following statements is/are correct for the coordination compound

K_{2} [C r (N H_{3}) (C N)_{4} (N O)] ?

(spin only magnetic moment for the compound is

1.732 B M

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