Write the main products of the following reactions:
(i) $C_{6} H_{5} N_{2}^{+} C l^{-} H_{3} P O_{2} + H_{2} O - ------- \to$ ?
(ii) & (iii) (Ref. image)

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Solution

(i) $C_{6} H_{5} \oplus N C I^{⊝} H_{3} P O_{2} + H_{2} O - ------- \to C_{6} H_{6} + N_{2} + H_{3} P O_{3} + H C l$
Products are Benzene, Nitrogen gas, Phosphorous acid Hydrochloric acid.

(ii) Product is 2, 4, 6-Tribromoaniline (Ref. image)

(iii) $\begin{matrix} C H_{3} & - & C & - & N H_{2} B r_{2} + N a O H - ------ \to C H_{3} - N H_{2} + N a_{2} C O_{3} + 2 N a B r + 2 H_{2} O | | O \end{matrix}$
Product are Methanamine, Sodium carbonate, Sodium bromide and water

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