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Question

Write the name, the structure and the magnetic behavior of each one of the following complexes:
(i) [Pt(NH3)Cl(NO2)]
(ii) [Co(NH3)4Cl2]Cl
(iii) Ni(CO)4
(At. Nos. Co=27,Ni=28,Pt=78)

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Solution

(i) [Pt(NH3)2ClNO2]: Diamminechloridonitrito-N-platinum (II); Pt2+=5d8


Structure = Square planar;
Magnetic behaviour : Diamagnetic

(ii) [CO(NH3)4Cl2]Cl: Tetraamminedichloridocobalt (III) chloride; Co3+=3d6


Structure = Octahedral
Magnetic behaviour : Diamagnetic

(iii) Ni(CO)4; Tetra carbonyl nikel (O); Ni=3d8,4s2


Structure = Tetrahedral;
Magnetic behaviour : Diamagnetic


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