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Byju's Answer
Standard XII
Chemistry
Factors Affecting Rate of Reaction
Write the rat...
Question
Write the rate law for the reaction
A
+
B
→
C
, from the following data:
What is the value of k?
Initial [A]/M
Initial [B]/M
Initial rate/
M
s
−
1
0.4
0.2
4.0
×
10
−
5
0.6
0.2
6.0
×
10
−
5
0.8
0.4
3.2
×
10
−
4
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Solution
[
A
]
[
B
]
Rate
0.4
0.2
4.0
×
10
−
5
0.6
0.2
6.0
×
10
−
5
0.8
0.4
3.2
×
10
−
4
A)
∴
R
a
t
e
=
K
[
A
]
1
[
B
]
2
B) value of
K
=
R
a
t
e
[
A
]
[
B
]
2
=
4
×
10
−
5
×
10
3
0.4
×
0.04
=
10
−
2
4
=
0.25
×
10
−
2
=
2.5
×
10
−
3
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Similar questions
Q.
From the following data answer the questions:
Reaction:
A
+
B
→
P
[A] M
[B] M
Initial rate
M sec
−
1
300
K
400
K
2.5
×
10
−
4
3.0
×
10
−
5
5.0
×
10
−
4
2.0
×
10
−
3
5.0
×
10
−
4
6.0
×
10
−
5
4.0
×
10
−
3
1.0
×
10
−
3
6.0
×
10
−
5
1.6
×
10
−
2
The value of rate constant at 300 K is
(
m
−
2
s
e
c
−
1
)
Q.
From the following data answer the questions:
Reaction:
A
+
B
→
P
[A]M
[B]M
Initial rate
M sec
−
1
300
K
400
K
2.5
×
10
−
4
3.0
×
10
−
5
5.0
×
10
−
4
2.0
×
10
−
3
5.0
×
10
−
4
6.0
×
10
−
5
4.0
×
10
−
3
1.0
×
10
−
3
6.0
×
10
−
5
1.6
×
10
−
2
The energy of activation for reaction
(
k
J
/
m
o
l
)
is:
Q.
For the reaction A + B
→
C; starting with different initial concentration of A and B, initial rate of reaction were determined graphically in four experiments.
S
l
.
N
o
[
A
]
0
/
M
(
I
n
i
t
i
a
l
c
o
n
c
.
)
[
B
]
0
/
M
(
I
n
i
t
i
a
l
c
o
n
c
.
)
R
a
t
e
/
(
M
s
e
c
−
1
)
1.
1.6
×
10
−
3
5
×
10
−
2
10
−
3
2.
3.2
×
10
−
3
5
×
10
−
2
4
×
10
−
3
3.
1.6
×
10
−
3
10
−
1
2
×
10
−
3
4.
3.2
×
10
−
3
10
−
1
8
×
10
−
3
Rate law for reaction from above data is
Q.
From the following data answer the questions:
Reaction: A + B
→
P
[A]M
[B]M
Initial rate
M sec
−
1
300 K
400 K
2.5
×
10
−
4
3.0
×
10
−
5
5.0
×
10
−
4
2.0
×
10
−
3
5.0
×
10
−
4
6.0
×
10
−
5
4.0
×
10
−
3
1.0
×
10
−
3
6.0
×
10
−
5
1.6
×
10
−
2
The order w.r.t A is:
Q.
Following data are given for the reaction between
A
and
B
.
[
A
]
/
m
o
l
L
−
1
[
B
]
/
m
o
l
L
−
1
Initial rate/
m
o
l
L
−
1
s
−
1
at
300
K
320
K
2.5
×
10
−
4
3.0
×
10
−
5
5.0
×
10
−
4
2.0
×
10
−
3
5.0
×
10
−
4
6.0
×
10
−
5
4.0
×
10
−
3
-
1.0
×
10
−
3
6.0
×
10
−
5
1.6
×
10
−
2
-
The rate constant at
300
K
is:
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