SOLUBILITY:
It is a measure of extent to which a compound will dissolve in a given solvent at constant temperature.
SOLUBILITY PRODUCT:
The equilbrium between a solid ionic salt and its saturated aqueous solution is described by the solubility product expression.
BaSO4 is a slightly soluble salt. When a reasonable quantity of solid BaSO4 is mixed with water, only a very small amount will dissolve to produce Ba+2 (aq) and SO4–2(aq).
BaSO4(s) <=> Ba+2(aq) + SO4–2(aq)).
Then the solubility product expression is,
Ksp= [Ba2+(aq)][SO4^-2 (aq)]