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Question

Write the structural formulae of probable isomeric alcohols having molecular formula C4H10O. What is the action of sodium-amalgam and water on ethyl methyl ketone?

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Solution

The probable isomers of alcohols having molecular formula C4H10O are four i.e. 2-butanol, 1-butanol, 2-methyl-2-propanol, and 2-methyl-1-propanol.
CH3CH2C|OH2butanolHCH3,CH3CH2CH2OH1butanol,CH3OH|C|CH32methyl2PropanolCH3,CH3CH3|CHCH2OH2methyl1Propanol
Ketones reduces to alcohol by the action of nascent hydrogen supplied by sodium analgam and water.
CH3CH2O||CCH3EthylmethylketoneNaHg/H2OCH3CH2C|OHHCH3Butan2ol

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