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Preparation of Alkyl Halides

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Question

Write the structure of the alkyl halide obtained by the action of hydrogen bromide on pent-1-ene
a) In presence of peroxide
b) In absence of peroxide

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Solution

(a) in presence of peroxide
$C H_{3} - C H = C H_{2} H B r - --- \to H_{2} O_{2} x C H_{3} - C H_{2} - C H_{2} B r$

(b) in absence of peroxide

$C H_{3} - C H = C H_{2} H B r \to C H_{3} - C H_{2} - C H_{2} B r + . B r .$

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