Write the structure of the major organic product in each of the following reactions-i CH 3 CH 2 CH 2 Cl - NaI actene - heatii CH 33 CBr - KOH ethanol - heatiii CH 3 CH Br CH 2 CH 3- NaOH waler -iv CH 3 CH 2 Br - KCN aquelanolv C 6 H 5 ONa - C 2 H 5 Cl -vi CH 3 CH 2 CH 2 OH - SOCl 2-vii CH 3 CH 2 CH - CH 2- HBr Peraxide -viii CH 3 CH - C CH 32- HBr -

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Halogenation of Alpha Carbon

Write the str...

Question

Write the structure of the major organic product in each of the following reactions:

(i)

(ii)

(iii)

(iv)

(v)

(vi)

(vii)

(viii)

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C H_{3} C H_{2} C H_{2} C l + N a I a c e t o n e - --- \to h e a t

(C H_{3})_{3} C B r + K O H e t h a n o l - --- \to h e a t

C H_{3} C H (B r) C H_{2} C H_{3} + N a O H w a t e r - -- \to

(C H_{3})_{3} C B r + K O H e t h a n o l - --- \to h e a t

C_{6} H_{5} O N a + C_{2} H_{5} C l ⟶

C H_{3} C H_{2} C H_{2} O H + S O C l_{2} ⟶

C H_{3} C H_{2} C H = C H_{2} + H B r p e r o x i d e - ---- \to

C H_{3} C H = C (C H_{3})_{2} + H B r ⟶

C H_{3} C H_{2} C H_{2} C l + N a I A c e t o n e - ---- \to

(C H_{3})_{3} C B r + K O H E t h a n o l, h e a t - ------- \to

C H_{3} C H (B r) C H_{2} C H_{3} + K O H W a t e r - --- \to

C H_{3} C H_{2} B r + K C N A q . e t h a n o l - ----- \to

C H_{3} C H = C H_{2} \to C H_{3} C H_{2} C H_{2} O H

Predict the products of the following reactions:

(i)

(ii)

(iii)

(iv)

	Column I		Column II
A.	$C H_{3} (C H_{2})_{3} O H N a B r - ----- \to H_{2} S O_{4}, Δ$	(i)	$C H_{3} C H (B r) (C H_{2})_{2} C H_{3}$
B.	$(C H_{3})_{3} C O H C o n c . H C l - ---------- \to r o o m t e m p e r a t u r e$	(ii)	$C H_{3} C H_{2} C H_{2} C l$
C.	$C H_{3} C H (O H) (C H_{2})_{2} C H_{3} P B r_{3} - -- \to$	(iii)	$(C H_{3})_{3} C C l$
D.	$C H_{3} C H_{2} C H_{2} O H S O C l_{2} - --- \to$	(iv)	$C H_{3} C H (B r) C H_{2} C H_{3}$

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