Write the structure of the major organic product isolated from the reaction of 3-hexyne with Chlorine(1 mol):

trans-3,4-dichloro-3-hexene

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cis-3,4-dichloro-3-hexene

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trans-2,4-dichloro-3-hexene

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cis-2,4-dichloro-3-hexene

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Solution

The correct option is A trans-3,4-dichloro-3-hexene
The major organic product isolated from the reaction of 3-hexyne with Chlorine (1 mole) is trans-3,4-dichloro-3-hexene.
Its structure is as shown.The addition of chlorine molecule to triple bond is trans.

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