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Question

Write the structures of aldehydes that are obtained on ozonolysis of :
(i) but-1-ene and
(ii) but-2-ene

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Solution

1) but-1-ene
CH2=CHCH2CH3O3−−−−Zn/H2OCH2O+CH3CH2CHO
ii) but-2-ene
CH3CH=CHCH3O3−−−−Zn/H2O2CH3CHO
On ozonolysis of But-1-ene followed by the hydrolysis, we get formaldehyde and acetaldehyde as a product.
Whereas on ozonolysis of but-2-ene followed by hydration we get acetaldehyde as a product.

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