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Isomerism in Coordination Compounds

Write the typ...

Question

Write the types of isomerism exhibited by the following complexes.
(i) $[C o (N H_{3})_{5} C l] S O_{4}$
(ii) $[C o (e n)_{3}]^{3 +}$
(iii) $[C o (N H_{3})_{6}] [C r (C N)_{6}]$

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Solution

(i) Ionisation isomerism
(ii) Optical isomerism(see diagram)
(III) Coordination isomerism

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Q. Name the type of isomerism exhibited by the following isomers :

[C r (N H_{3})_{6}] [C o (C N_{6})]

[C o (N H_{3})_{6}] [C r (C N)_{6}]

Q. The isomerism exhibited by following compounds

[C o (N H_{3})_{6}] [C r (C N)_{6}]

[C r (N H_{3})_{6}] [C o (C N)_{6}]

Q. What type of isomerism is exhibited the complex

[C o (N H_{3})_{5} C l] S O_{4}

Q. What type of isomerism is exhibited by the complex

[C o (N H_{3})_{5} C l] S O_{4}

?

Q. (a) Write the formula of the following coordination compound :

Iron(III) hexacyanoferrate(II)

(b) What type of isomerism is exhibited by the complex

[C o (N H_{3})_{5} C l] S O_{4}

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(c) Write the hybridisation and number of unpaired electrons in the complex [

C o F_{6}]^{3 -}

. (Atomic No. of Co = 27)

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