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Reaction with Metals

Wurtz reactio...

Question

Wurtz reaction involves the reduction of alkyl halide with ____ in ether.

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Solution

Wurtz reaction involves the reduction of an alkyl halide with Na in ether. Wurtz reaction is a convenient method for the preparation of symmetrical alkanes (R-R) i.e. alkane containing even the number of C atoms.

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Q. Wurtz reaction involves the reduction of alkyl halide with

Q. In Wurtz reaction alkyl halide react with:

t

-Butyl romide on reaction with sodium metal in dry ether gives

2, 2, 3, 3

-tetramethyl butane Reason:

t

-Alkyl halides readily undergo Wurtz reaction.

Q. Assertion :Wurtz's coupling reaction of alkyl halide is not suitable for an alkane containing an odd number of carbons in the parent chain. Reason: Wurtz's coupling reaction involves heating of alkyl halides with sodium metal in dry ether.

In Wurtz reaction of alkyl halides with sodium the reactivity order of these halides is:

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