X2O4(l)⟶2XO2(g),ΔU=2.1kcal ΔS=20calK−1 at 300 K. Then ΔG is:
A
2.7 kcal
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B
-2.7 kcal
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C
9.3 kcal
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D
-9.3 kcal
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Solution
The correct option is B -2.7 kcal The given reaction is, X2O4(l)⟶2XO2(g)Δng=2−0=2 Again given, ΔU=2.1kcalΔS=20calK−1T=300K We know, ΔH=ΔU+ΔngRT=2.1×1000+2×2×300=2100+1200=3300cal Again, ΔG=ΔH−TΔS=3300−300×20=3300−6000=−2700calor−2.7kcal