(x)CH3−O||S||−OO−H(y)CH3−O||C−O−H(z)CH3−OH Set the following in increasing order of their pKa values.
A
y<x<z
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B
x<y<z
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C
y<z<x
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D
x<z<y
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Solution
The correct option is Bx<y<z Since x and y are stabilized by resonance, they have higher Ka values than Z. Further x is more stabilized than y owing to one more resonance structure. Hence, order of Ka is x>y>z Here the Ka, less is pKa[∵pKa=−logKa] ∴ Order of pKa is x<y<z