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Question

(x) CH3−O||S||−OO−H (y) CH3−O||C−O−H (z) CH3−OH
Set the following in increasing order of their pKa values.

A
y<x<z
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B
x<y<z
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C
y<z<x
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D
x<z<y
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Solution

The correct option is B x<y<z
Since x and y are stabilized by resonance, they have higher Ka values than Z. Further x is more stabilized than y owing to one more resonance structure.
Hence, order of Ka is x>y>z
Here the Ka, less is pKa[pKa=logKa]
Order of pKa is x<y<z
1053071_988202_ans_9bcee2742f8c43b082ec08112a9e54db.PNG

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