Xample- anZn- 4s and 3d e experience different effective nuclear charge4s- - 10 x 1-0 - 18 x 0-85 - 1 x 0-35 25-65For eZ 30-25-65 4-353d- -181-0 - 9 x 0-35-21-15Z 30-21-15 8-85

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Cationic Radius

xample, anZn,...

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xample, anZn, 4s and 3d e experience different effective nuclear charge4s, σ 10 x 1.0 + 18 x 0.85 + 1 x 0.35 25.65For eZ 30-25.65 4.353d, σ-181.0 + 9 x 0.35-21.15Z 30-21.15 8.85

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Find $x$ and $y$ in the given figure.

\frac{0.5 (x - 0.4)}{0.35} - \frac{0.6 (x - 2.71)}{0.42} = x + 61

Z^{*}

Z^{*} = Z - σ

σ

NaF

F^{-}

(130 + x)

x

\frac{Σ f d x d y - \frac{Σ f d x Σ f d y}{N}}{\sqrt{Σ f d x^{2} - \frac{(Σ f d x)^{2}}{N}} \sqrt{Σ f d y^{2} - \frac{(Σ f d y)^{2}}{N}}}

r = 0.6745 \frac{{- r}^{2}}{\sqrt{N}}

r = 1 - \frac{6 Σ d^{2}}{n (n^{2} - 1)}

r = \frac{Σ x y}{N σ x σ y}

σ

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