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Question

XeF6 cannot be stored in quartz or silica vessel, NaOH cannot be stored in a glass vessel and HF cannot be stored in a glass vessel.

A
True
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B
False
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Solution

The correct option is A True
XeF6 is very reactive and cannot be stored in quartz or silica vessel because it reacts with them and forms an explosive compound (XeO3).
2XeF6+SiO22XeOF4+SiF4
2XeOF4+SiO22XeO2F2+SiF4
2XeO2F2+SiO22XeO3+SiF4

Storing strong NaOH in glass vessel results in a reaction between NaOH and glass, resulting in the formation of sodium silicate.
NaOH+SiO2Na2SiO3+H2O

HF also cannot be stored in glass bottles because it attacks the silicates (like sodium silicate) in glass.
Na2SiO3+8HFH2SiF6+2NaF+3H2O

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