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Question

You are given a colourless solution and was told to add a little NaCl solution to it. A cloudy white precipitate was made. What conclusion should you draw about the nature of the colourless solution? The ppt dissolves in hot water, then the ppt is :

A
AgCl
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B
PbCl2
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C
Ag2SO4
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D
PbSO4
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Solution

The correct option is B PbCl2
It is given that a colourless solution gives cloudy white precipitate on adding a little NaCl solution. Now, white ppt can be of AgCl or PbCl2.
To make further distinction, warm the solution.
PbCl2 dissolves in hot water while AgCl remains insoluble. AgCl dissolves in aq NH3.
Since the ppt dissolves in hot water, it is PbCl2.

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