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Question

You are provided with a mixture of naphthalene and ammonium chloride by your teacher. Suggest an activity to separate them with a well-labelled diagram.


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Solution

Sublimation:

  • The phase transition which takes place directly from solid into a vapor is known as sublimation.

Activity:

Properties of naphthalene and ammonium chlorideNH4Cl:

  • Naphthalene is insoluble in water but soluble in an organic solvent. It changes into vapors at room temperature.
  • Ammonium chloride is soluble in water but insoluble in benzene. It changes into vapors on heating.

Procedure:

  • Add water to ammonium chloride in order to make a mixture.
  • Filter the mixture. Naphthalene is obtained as residue while ammonium chloride is collected as filtrate.
  • Crystallize the filtrate by heating till a saturated solution of ammonium chloride is obtained.
  • Cool the hot saturated solution to get crystals of ammonium chloride.

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