Dear Student
1.) The black substance is formed because of the oxidation of copper.
2.) The black substance is copper (II) oxide (CuO).
3.) 2Cu + O2→ 2CuO
When hydrogen is passed over it, hydrogen displaces oxygen from copper oxide restoring back the brown colour of the copper.
The reverse reaction is
CuO + H2—–> Cu + H2O
Regards