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Question

Z is a compound. With dilute HCl it gives a gas turning dichromatic solution green. Z gives lilac flame. Name Z.

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Solution

'Z' is potassium sulphite (K2SO3). It burns with a lilac or pink flame. When potassium sulphite is warmed with dilute HCl, it reacts and releases sulphur dioxide gas, which turns dichromate solution (orange colour) green. The equation for the reaction between potassium sulphite and dilute HCl is given below:

K2SO3 (aq) + 2 HCl (aq) 2 KCl (aq) + H2O (l) + SO2 (g)Potassium Potassium Sulphur dioxidesulphite chloride 3SO2 (g) + K2Cr2O7 (aq)+ H2SO4 (aq) K2SO4 (aq) + Cr2SO43 (aq) + H2O (l)Sulphur Acidified Potassium Potassium Chromium dioxide dichromate sulphate sulphate

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