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Byju's Answer
Standard XII
Chemistry
Aufbau Principle
Zn2+ salts ar...
Question
Z
n
2
+
salts are white while
C
u
2
+
salts are coloured. Why?
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Solution
The electronic configuration of
Z
n
2
+
and
C
u
2
+
can be given as follow:
Z
n
2
+
:
[
A
r
]
3
d
10
C
u
2
+
:
[
A
r
]
3
d
9
Here
C
u
2
+
has one unpaired electron while
Z
n
2
+
have all paired electrons.
In d-block elements, the element which has an unpaired electron shows colour.
Thus
C
u
2
+
show colour.
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2
Similar questions
Q.
Give reason:
Z
n
2
+
salts are white
C
u
2
+
salts are blue.
Q.
(A) Account for the following:
(i)
M
n
shows the highest oxidation state of +7 with oxygen but with fluorine, it shows oxidation state of +4.
(ii)
C
r
2
+
is a strong reducing agent.
(iii)
C
u
2
+
salts are coloured, while
Z
n
2
+
salts are white.
(B) Complete the following equations:
(i)
2
M
n
O
2
+
4
K
O
H
+
O
2
Δ
→
(ii)
C
r
2
O
2
−
7
+
14
H
+
+
6
e
−
→
Q.
C
u
2
+
ions are coloured, but
Z
n
2
+
ions are colourless. Why?
Q.
Why
S
c
3
+
salts are colorless whereas
C
r
3
+
salt are coloured?
Q.
a. Why
3
d-series of elements acts as good catalyst?
b. Given reason:
T
i
4
+
salts are colourless where as
C
r
3
+
salts are coloured.
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