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Question

Zn amalgam is prepared by the electrolysis of aqueous ZnCl2 using Hg cathode (9g). How much current is to be passed through ZnCl2 solution for 1000 seconds to prepare a Zn amalgam with 25% Zn by weight? (Zn= 65.4)

A
5.6 amp
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B
7.2 amp
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C
8.85 amp
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D
11.2 amp
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Solution

The correct option is C 8.85 amp
Let x gm of Zn deposit on 9 gm of Hg
% of Zn in Amalgam =mZn×100mZn+mHg=x9+x×100=25
x=3gm
Equivalence of Zn=3×265.4
Q2F=it2F
Current, i=Eeq×Ft=665.4×965001000=8.85 amp

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