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Byju's Answer
Standard XII
Chemistry
SHE
Zn s / Z n 2...
Question
Z
n
(
s
)
/
Z
n
2
+
(
a
q
)
∥
C
u
2
+
(
a
q
)
/
C
u
(
s
)
E
0
Z
n
2
+
/
Z
n
=
−
0.76V,
E
0
C
u
2
+
/
C
u
=
+
0.34V.
Calculate
E
0
c
e
l
l
and equilibrium constant
K
.
Open in App
Solution
E
0
c
e
l
l
=
E
0
c
a
t
h
o
d
e
+
E
0
a
n
o
d
e
= 0.34+0.76
= 1.1 V
E
0
=
0.0591
n
l
o
g
K
1.1 =
0.0591
2
l
o
g
K
K =
1.67
×
10
37
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0
Similar questions
Q.
Calculate
E
∘
values of following reactions:
C
u
(
s
)
+
Z
n
2
+
(
a
q
)
→
Z
n
(
s
)
+
C
u
2
+
(
a
q
)
[Given:
E
0
C
u
2
+
/
C
u
=
0.34
V
,
E
0
Z
n
2
+
/
Z
n
=
−
0.76
V
]
Q.
Calculate
E
o
C
e
l
l
value of the following reactions:
Z
n
(
s
)
+
C
u
2
+
(
a
q
)
→
Z
n
2
+
(
a
q
)
+
C
u
(
s
)
[Given:
E
∘
C
u
2
+
/
C
u
=
0.34
V
,
E
∘
Z
n
2
+
/
Z
n
=
−
0.76
V
]
Q.
E
∘
for the cell,
Zn(s)|Zn
2
+
(
aq
)
|
|
Cu
2
+
(aq)|Cu(s)
is
1.10
V at
25
∘
C
. The equilibrium constant for the reaction,
Zn(s)
+
Cu
2
+
(aq)
→
Cu(s)
+
Zn
2
+
(aq)
is
1.94
×
10
x
. The value of
x
is
Q.
If excess of
Z
n
is added to
1.0
M
solution of
C
u
S
O
4
, find the concentration of
C
u
2
+
ions at equilibrium.
Given:
E
0
(
Z
n
2
+
|
Z
n
)
=
−
0.76
V
,
E
0
(
C
u
2
+
C
u
)
=
−
0.34
V
Q.
E
∘
for the electrochemical cell,
Z
n
(
s
)
|
Z
n
2
+
1
M
(
a
q
.
)
∥
C
u
2
+
1
M
(
a
q
.
)
|
C
u
(
s
)
is
1.10
V
at
25
∘
C
. The equilibrium constant for the cell reaction,
Z
n
(
s
)
+
C
u
2
+
(
a
q
.
)
⇌
Z
n
2
+
(
a
q
.
)
+
C
u
(
s
)
will be:
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