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Question

Draw the resonance structure of nitro benzene.


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Solution

Resonating structure:

  • Electrons in an atom do not have a fixed position but they have the probability of being available in a certain region.
  • Resonance describes the high probability of the occurrence of electrons in a certain region.
  • Resonating structures are a set of two or more than two Lewis structures that describes the bonding in a polyatomic compound.
  • Resonating structures also describe the delocalized electrons that cannot be described in a single Lewis structure.

Nitrobenzene:

  • In Nitrobenzene, an electron-withdrawing group is present on the phenyl ring which makes the ring has a lower electron density than Benzene.
  • Because of the electron-withdrawing group, the phenyl ring is less nucleophilic than Benzene.
  • The double bond present between the Nitrogen atom and the Carbon atom allows the electron density to be delocalized across the atoms.
  • As shown in the resonance, the ortho and para position gets positive.
  • As a result, the meta position gets activated for electrophilic substitution reaction and electrophile attacks at the meta position.

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