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Question

Given below are the standard electrode potentials of a few half-cells. K+/K=-2.93V,Ag+/Ag=0.80V,Mg2+/Mg=2.37V,Cr3+/Cr=0.74V. What will be the correct order of these metals in increasing reducing power?


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Solution

Redox potential

  • Redox potential is a measure of tendency of chemical species to get reduced or oxidised by gaining or losing electrons to an electrode.

Reducing power

  • Reducing power is the potential of a substance to reduce another substance.
  • More the oxidation potential the element will have more tendency to get oxidised.
  • Reduction potential of half cells are:

K+/K=-2.93VAg+/Ag=0.80VMg2+/Mg=2.37VCr3+/Cr=0.74V

  • The more easily it removes electrons or higher the reduction potential higher is its reducing power, the more it will reduce other substance.
  • Order of these metals in increasing reducing powers is Ag<Cr<Mg<K.

Therefore, potassium has lowest reduction potential, therefore, it can donate electrons easily and reduces other substance.


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