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Question

How to calculate valency of nitrate?


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Solution

Valency:-

  • Valency is known as the capacity of an atom or a molecule to combine.
  • To calculate valency of an atom or a molecule we consider the electrons present in the valence shell, i.e. outermost shell.

Valency of nitrate:-

  • NO3- (Nitrate ion) has three oxygen atoms and one nitrogen atom.
  • Structure of nitrate ion
  • Nitrogen belongs to group -15 in the periodic table, forms bonds with three oxygen atoms.
  • Since Nitrogen can form only 3 bonds, the formation of 4 bonds leads to a positive charge of +1.
  • Oxygen belongs to the group – 16 in the periodic table, thus, it has a valency (-2), and forms 2 bonds.
  • From the structure, it is clear that the positive charge on nitrogen atom is balanced by the negative charge on 1 oxygen atom, and 1 extra charge is left. Therefore Nitrate ion have 1 charge or valency.

Therefore, valency of nitrate ion is 1.


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