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Question

Is pyridine an aromatic compound?


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Solution

Aromatic compound:

  • A compound is known to be an aromatic compound if it is flat, cyclic, and conjugated and also obeys Huckel’s rule.
  • Huckel's rule states to be called as aromatic, an organic compound should have pi electrons in the overlapping p orbitals.

Aromaticity of pyridine:

  • The π orbital system of pyridine has p electrons that are delocalized throughout the ring, making it planar.
  • It also has 4n+2 delocalized p electrons, where n=1 .
  • Pyridine has a planar structure because itsporbitals are perpendicular to the ring.
  • Also, it is a cyclic compound and it matches all the criteria of an aromatic compound, which makes it an aromatic compound.
  • The structure of pyridine is given below:


  • Also the protons of pyridine display chemical shifts in the NMR spectrum that are typical of aromatic protons.
  • As an aromatic compound, pyridine may also participate in electrophilic substitutions as an electrophile.

Therefore, yes, pyridine is an aromatic compound.


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