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Question

What do the dextro and levo prefixes mean in Latin?


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Solution

Understanding the concept:

  • The Latin word dexter is the source of the prefix dextro. It denotes being to the right(d) or on the right side.
  • The Latin word laevo is where the prefix Levo originates. It denotes being to the left(l)or on the left.

Explanation of dextro(d) and levo(l) :

  • The plane of polarisation rotates with the same angles but in the opposite direction for a pair of enantiomers with the same concentration and under the same circumstances.
  • One moves in a clockwise direction, the other in a counterclockwise direction.
  • The enantiomer is designated with the prefix (d) or (+) and said to be dextrorotatory (Latin, which means to the right) since it rotates the plane of polarisation clockwise.
  • The enantiomer is designated with the prefix (l) or (-) and is known as levorotatory (Latin, which means to the left) since it rotates the plane of polarisation counterclockwise.
  • These are different from capital D and Lnotations( represent the presence of a -OHgroup in a sugar molecule).
  • For example, The second-to-last carbon's position of the hydroxyl group in sugars affects whether it is a D- sugar or Lsugar.
  • D-sugars are those that have the hydroxyl group on the right side of that carbon atom, while L-sugars have the hydroxyl group on the left.

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