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Question

What is CMC and Kraft temperature?


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Solution

Critical Micelle Concentration

  • Critical Micelle Concentration (CMC) is the concentration above which micelle formation occurs.
  • The minimum quantity of surfactant needed to lower the maximum surface tension of water is determined using CMC.

Example of Critical Micelle Concentration

  • The value of CMC for sodium dodecyl sulfate in water at 25°C, atmospheric pressure, is 8x10-3molL-1.

Kraft Temperature

  • The term "Kraft Temperature" refers to the temperature at which a surfactant's solubility is equal to its critical micelle concentration.
  • Kraft Temperature is also called critical micelle temperature or Kraft point.

Example of kraft temperature

  • Above the kraft temperature, the aqueous solution of detergents starts boiling.

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